Wulfenite
- Named in honour of Franz Xavier Wulfen (1728–1805), Austrian–German Jesuit, who wrote a monograph on the lead ores of Bleiberg, Austria.
- Wulfenite was voted “Mineral of the Year” in Austria in 2020.
- In its pure form wulfenite is colorless; the often yellow to red colour is most probably due to trace amounts of chromium substituting Mo.
- Formula: PbMoO4
- Space group: I41/a (No. 88)
- Crystal system: tetragonal
- Crystal class: 4/m
- Lattice parameters: a = b = 5.434 Å, c = 12.107 Å, α = β = γ = 90°

Modified by CombineZP
Picture: Didier Descouens – CC BY-SA 4.0
https://commons.wikimedia.org/w/index.php?curid=12426342
Crystal structure (click on the picture to download the VESTA file):
(K. Momma and F. Izumi, “VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data,”J. Appl. Crystallogr., 44, 1272-1276 (2011).)
- PbO8 coordination environment
- MoO4 tetrahedra (blue)
- Pb (black)
- Oxygen (red)
For a 3D interactive version on sketchfab, see here:
Reference:
Natural wulfenite: structural refinement by single-crystal X-ray diffraction
C. Lugli, L. Medici, D. Saccardo,
Neues Jahrbuch fur Mineralogie, Monatshefte 1999, 6, 281-288
Yes, the color change is caused by the Cr substitution. Here is the paper with more details about color and also presence of OH groups in wulfenite: https://www.researchgate.net/profile/Dominik_Talla/publication/257391396_On_the_presence_of_hydrous_defects_in_differently_coloured_wulfenites_PbMoO4_An_infrared_and_optical_spectroscopic_study/links/54b12bc40cf28ebe92dff6aa/On-the-presence-of-hydrous-defects-in-differently-coloured-wulfenites-PbMoO4-An-infrared-and-optical-spectroscopic-study.pdf
Thank you very much for your contribution and for pointing to the paper!
best wishes
Frank