Antarcticite

Antarcticite

  • named after the type locality – the Don Juan Pond in Antarctica
  • Antarcticite is very hygroscopic and is formed only in very arid regions and precipitates only from highly saline brines
  • Formula: CaCl2  · 6 H2O
  • Space group: P321
  • Crystal system: trigonal
  • Crystal class: 32
  • Lattice parameters: a = b =  7.8759(2) Å, c = 3.9545(2) Å, α = β = 90°, γ  120°

Crystal structure (click on the pictures to download the VESTA file):

(K. Momma and F. Izumi, “VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data,” J. Appl. Crystallogr., 44, 1272-1276 (2011).)

  • every Ca ion is surrounded by nine water molecules
  • the CaO9 polyhedra (blue) are face-connected and stacked along the c axis
  • these faces are made up of three water molecules  acting as bridging ligands between two Ca ions
  • every Cl anion is involved in 6 H-bonds (dotted lines)
  • Oxygen (red)
  • Chlorine (green)
  • Hydrogen (white)

For a 3D interactive version, see here:

https://skfb.ly/6PJXV

Refs:

[1] T. Torii, J. Ossaka, Science 1965, 149, 975-977.
DOI: 10.1126/science.149.3687.975

[2] P. A. Agron, W. R. Busing, Acta Crystallogr. C 1986, 42, 141-143.
DOI: 10.1107/S0108270186097007

Leave a Reply

Fill in your details below or click an icon to log in:

WordPress.com Logo

You are commenting using your WordPress.com account. Log Out /  Change )

Twitter picture

You are commenting using your Twitter account. Log Out /  Change )

Facebook photo

You are commenting using your Facebook account. Log Out /  Change )

Connecting to %s